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2024.11.26 Tuesday

Breakthrough in Clean Energy: Scientists Pioneer Novel Heat-to-Electricity Conversion

Researchers demonstrated for the first time transverse thermoelectric conversion in the semimetal WSi2, leading to more efficient thermoelectric devices

Breakthrough in Clean Energy: Scientists Pioneer Novel Heat-to-Electricity Conversion

Thermoelectric materials, which convert heat into electricity, are valuable tools for capturing waste heat and turning it into usable electricity. These materials are especially useful in industries and vehicles where engines produce a lot of waste heat, improving energy efficiency by converting it into additional power. They also exhibit potential for portable power generation, in remote sensors and satellites where traditional power sources may be impractical.

Traditional thermoelectric devices, known as parallel thermoelectric devices, generate a voltage in the same direction as the heat flow. These devices typically use two types of parallel materials, namely p- and n-type, which generate voltages in opposite directions. By connecting them in series, a stronger voltage can be generated. However, this also leads to a greater number of contact points, which increase electrical resistance and consequently, power loss. In contrast, transverse thermoelectric devices do something unique: they generate electricity perpendicular to the heat flow. This allows them to use fewer contacts and, hence, achieve a more efficient thermoelectric conversion. Materials with "axis-dependent conduction polarity (ADCP)" or goniopolar conductors, that conduct positive charges (p-type) in one direction and negative charge (n-type) in another, are promising candidates for transverse thermoelectric devices. Unfortunately, a direct demonstration of the transverse thermoelectric effect (TTE) has been less studied―until now.

In this view, a research team from Japan, led by Associate Professor Ryuji Okazaki from the Department of Physics and Astronomy at Tokyo University of Science (TUS), including Mr. Shoya Ohsumi from TUS and Dr. Yoshiki J. Sato from Saitama University, achieved TTE in the semimetal tungsten disilicide (WSi2). Although previous studies have shown that WSi2 exhibits ADCP, its origin and the anticipated TTE have not been detected in experiments. "Transverse thermoelectric conversion is a phenomenon that is gaining attention as a new core technology for sensors capable of measuring temperature and heat flow. However, there are only a limited number of such materials, and no design guidelines have been established. This is the first direct demonstration of the transverse thermoelectric conversion in WSi2," explains Prof. Okazaki. Their study was published online in the journal PRX Energy on November 13, 2024.

The researchers analyzed the properties of WSi2 through a combination of physical experiments and computer simulations. They measured the thermopower, electrical resistivity, and thermal conductivity of a WSi2 single crystal along its two crystallographic axes at low temperatures. They found that the ADCP of WSi2 originates from its unique electronic structure, featuring mixed-dimensional Fermi surfaces. This structure reveals that electrons and holes (positive charge carriers) exist in different dimensions. A Fermi surface is a theoretical geometrical surface that separates occupied and unoccupied electronic states of charge carriers inside a solid material. In WSi2, electrons form quasi-one-dimensional Fermi surfaces and holes form quasi-two-dimensional Fermi surfaces. These unique Fermi surfaces create direction-specific conductivity, enabling the TTE effect.

The researchers also observed variations in how these charge carriers conduct electricity from sample to sample, consistent with previous studies. Using simulations based on first principles, the researchers showed that these variations were due to differences in how charge carriers scatter due to imperfections in the crystal lattice structure of WSi2. This insight is key to fine-tuning the material and developing reliable thermoelectric devices. Further, they demonstrated direct TTE generation in WSi2 by applying a temperature difference along a specific angle relative to both crystallographic axes, resulting in a voltage perpendicular to the temperature difference.

"Our results indicate that WSi2 is a promising candidate for TTE-based devices. We hope this research will lead to the development of new sensors and the discovery of new transverse thermoelectric materials," says Prof. Okazaki.

By elucidating the mechanism of TTE generation in WSi2, this study takes a step further toward advanced materials that can convert heat into electricity more efficiently, leading to a greener future.

Breakthrough in Clean Energy: Scientists Pioneer Novel Heat-to-Electricity Conversion

Image title: Transverse thermoelectric generation in WSi2
Image caption: This paper is the first direct demonstration of the transverse thermoelectric generation in WSi2, and the results could pave the way for more efficient thermoelectric devices.
Image credit: Ryuji Okazaki from Tokyo University of Science, Japan
License type: Original Content
Usage restrictions: Cannot be reused without permission.

Reference
Title of original paper  : Transverse thermoelectric conversion in the mixed-dimensional semimetal WSi2
Journal  : PRX Energy
DOI  : 10.1103/PRXEnergy.3.043007
About The Tokyo University of Science

Tokyo University of Science (TUS) is a well-known and respected university, and the largest science-specialized private research university in Japan, with four campuses in central Tokyo and its suburbs and in Hokkaido. Established in 1881, the university has continually contributed to Japan's development in science through inculcating the love for science in researchers, technicians, and educators.

With a mission of "Creating science and technology for the harmonious development of nature, human beings, and society," TUS has undertaken a wide range of research from basic to applied science. TUS has embraced a multidisciplinary approach to research and undertaken intensive study in some of today's most vital fields. TUS is a meritocracy where the best in science is recognized and nurtured. It is the only private university in Japan that has produced a Nobel Prize winner and the only private university in Asia to produce Nobel Prize winners within the natural sciences field.

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About Associate Professor Ryuji Okazaki
from Tokyo University of Science

Dr. Ryuji Okazaki is currently an Associate Professor at the Department of Physics and Astronomy at the Tokyo University of Science, Japan. He received his M.S. and Ph.D. degrees from Kyoto University, Japan, in 2008 and 2013, respectively. He has published over 140 articles that have received over 3,400 citations, including a feature article in the journal Applied Physics Letters. He is the recipient of the Papers of Editors' Choice by JPSJ in 2017 from The Physical Society of Japan and the 2013 Springer Theses Award. His research is focused on correlated electron systems and condensed matter physics.
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Funding information

This work was partly supported by JSPS KAKENHI Grant No. 22K20360, No. 22H01166, and No. 24K06945, and Research Foundation for the Electrotechnology of Chubu (REFEC, No. R-04102).

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