Tokyo University of Science


2020.11.18 Wednesday

Spintronics AdvancesーControlling Magnetization Direction of Magnetite at Room Temperature

Scientists develop an energy-efficient strategy to reversibly change "spin orientation" or magnetization direction in magnetite at room temperature

Spintronics-based on the principles of electron charge and magnetic spin-goes beyond the limits of conventional electronics. However, spintronic devices are yet to see advances, because controlling the magnetization angle in the magnetic material is difficult. Now, scientists have developed an all-solid redox device composed of magnetite thin film and a solid electrolyte containing lithium ions that successfully manipulated the magnetization angle at room temperature, sparking a possible revolution in the field of spintronics.

Over the last few decades, conventional electronics has been rapidly reaching its technical limits in computing and information technology, calling for innovative devices that go beyond the mere manipulation of electron current. In this regard, spintronics, the study of devices that exploit the "spin" of electrons to perform functions, is one of the hottest areas in applied physics. But, measuring, altering, and, in general, working with this fundamental quantum property is no mean feat.

Current spintronic devices-for example, magnetic tunnel junctions-suffer from limitations such as high power consumption, low operating temperatures, and severe constraints in material selection. To this end, a team of scientists at Tokyo University of Science and the National Institute for Materials Science (NIMS), Japan, has recently published a study in ACS Nano, in which they present a surprisingly simple yet efficient strategy to manipulate the magnetization angle in magnetite (Fe3O4), a typical ferromagnetic material. The team fabricated an all-solid reduction-oxidation ("redox") transistor containing a thin film of Fe3O4 on magnesium oxide and a lithium silicate electrolyte doped with zirconium (Fig. 1). The insertion of lithium ions in the solid electrolyte made it possible to achieve rotation of the magnetization angle at room temperature and significantly change the electron carrier density. Associate Professor Tohru Higuchi from Tokyo University of Science, one of the authors of this published paper, says "By applying a voltage to insert lithium ions in a solid electrolyte into a ferromagnet, we have developed a spintronic device that can rotate the magnetization with lower power consumption than that in magnetization rotation by spin current injection. This magnetization rotation is caused by the change of spin-orbit coupling due to electron injection into a ferromagnet."

Unlike previous attempts that relied on using strong external magnetic fields or injecting spin-tailored currents, the new approach leverages a reversible electrochemical reaction. After applying an external voltage, lithium ions migrate from the top lithium cobalt oxide electrode and through the electrolyte before reaching the magnetic Fe3O4 layer. These ions then insert themselves into the magnetite structure, forming LixFe3O4 and causing a measurable rotation in its magnetization angle owing to an alteration in charge carriers.

This effect allowed the scientists to reversibly change the magnetization angle by approximately 10°. Although a much greater rotation of 56° was achieved by upping the external voltage further, they found that the magnetization angle could not be switched back entirely (Fig. 2). "We determined that this irreversible magnetization angle rotation was caused by a change in the crystalline structure of magnetite due to an excess of lithium ions," explains Higuchi, "If we could suppress such irreversible structural changes, we could achieve a considerably larger magnetization rotation."

The novel device developed by the scientists represents a big step in the control of magnetization for the development of spintronic devices. Moreover, the structure of the device is relatively simple and easy to fabricate. Dr Takashi Tsuchiya, Principal Researcher at NIMS, the corresponding author of the study says, "By controlling the magnetization direction at room temperature due to the insertion of lithium ions into Fe3O4, we have made it possible to operate with much lower power consumption than the magnetization rotation by spin current injection. The developed element operates with a simple structure."

Although more work remains to be done to take full advantage of this new device, the imminent rise of spintronics will certainly unlock many novel and powerful applications. "In the future, we will try to achieve a rotation of 180° in the magnetization angle," says Dr Kazuya Terabe, Principal Investigator at the International Center for Materials Nanoarchitectonics at NIMS and a co-author of the study, "This would let us create high-density spintronic memory devices with large capacity and even neuromorphic devices that mimic biological neural systems." Some other applications of spintronics are in the highly coveted field of quantum computing.

Only time will tell what this frontier technology has in line for us!

Spintronics Advances-Controlling Magnetization Direction of Magnetite at Room Temperature

Figure 1. After applying an external voltage, lithium ions flow through the reduction-oxidation transistor and reach the bottom magnetite film, altering its charge carrier concentration and modifying the orientation of Fe spins.

Spintronics Advances-Controlling Magnetization Direction of Magnetite at Room Temperature

Figure 2. The change in magnetization angle become noticeable under external voltages higher than 0.7 V, yielding a reversible change of about 10°. At voltages higher than 1.2 V, the rotation is more pronounced but becomes irreversible due to permanent structural changes in the magnetite phase.

Title of original paper  : Room-Temperature Manipulation of Magnetization Angle, Achieved with an All-Solid-State Redox Device
Journal  : ACS Nano
DOI  : 10.1021/acsnano.0c07906
About The Tokyo University of Science

Tokyo University of Science (TUS) is a well-known and respected university, and the largest science-specialized private research university in Japan, with four campuses in central Tokyo and its suburbs and in Hokkaido. Established in 1881, the university has continually contributed to Japan's development in science through inculcating the love for science in researchers, technicians, and educators.

With a mission of "Creating science and technology for the harmonious development of nature, human beings, and society", TUS has undertaken a wide range of research from basic to applied science. TUS has embraced a multidisciplinary approach to research and undertaken intensive study in some of today's most vital fields. TUS is a meritocracy where the best in science is recognized and nurtured. It is the only private university in Japan that has produced a Nobel Prize winner and the only private university in Asia to produce Nobel Prize winners within the natural sciences field.

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About Associate Professor Tohru Higuchi from Tokyo University of Science

Tohru Higuchi, one of the co-authors of this study, is a member of the Department of Applied Physics in the Tokyo University of Science. He graduated in Applied Physics from the Tokyo University of Science in 1995, where he then proceeded to obtain Master's and PhD degrees. His research mainly focuses on functional material science specializing in thin film/surface and interfacial physical properties and inorganic industrial materials. He has authored over 200 papers and received several awards, such as those for his contributions in the GREEN-2019 conference and the 2019 International Symposium on Advanced Material Research.


Funding information

This study was in part supported by Japan Society for the Promotion of Science (JSPS) KAKENHI grant number JP20H05301 (Grant-in-Aid for Scientific Research on Innovative Areas "Interface Ionics") and grant number JP19J13859 (Grant-in-Aid for JSPS Fellows). A part of this work was supported by NIMS TEM Station.


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